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Enantioselective man made tools aren't basically within the leading edge of chemical and pharmaceutical study yet task during this sector is continually expanding. it really is inspired via the urgency to acquire medicinal drugs or compounds of medicinal curiosity as unmarried anantiomers, and the keeness to synthesize average items in nonracemic shape. This quantity provides seven chapters from pioneers and gurus during this speedily increasing box.

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Pure Appl. Chem. ; Noyori, R. J. Am. Chem. Soc. 1989, HI, 4028. 48. ; Nakai, T. J. Chem. Soc, Chem. Commun. ; Terada, M. Tetrahedron Symposia in Print 1992,48, 5677. 49. Heathcock, C. H. Chem & Eng. News 1991, 3. 50. ; Caughlan, C. N. Inorg. Chem. 1966, 5, 1782. ; Takusagawa, F. Organometallics 1994, 13, 2218. 51. Figure 2 represents the 3-D representation rendered with the Macintosh program Chem-3D+. Bond lengths and angles of the Ti202 four membered ring and titanium binaphthoxide framework were initially based on the X-ray crystal analysis data for a similar type of diphenoxytitanium dichloride and diisopropoxytitanium binaphthoxide, which was generously presented by Professor K.

Chem. Soc. 1980,702,7385. 35. ; Michaelis, W. C) 1982,277,65. For the synthesis, see: Heathcock, C. ; Finkelstein, B. ; Jarvi, E. ; Radel, P. ; Hadley, C. R. /. Org. Chem. 1988,53,1922. 36. The selective functionalization of remote C-H or C-C bonds represents a great challenge. While such processes are common to enzymes which anchor a functional group and select a specific site of the substrate, only a few cases are reported for the nonenzymatic reactions. Breslow has coined the term "remote functionalization" for this method for alkane activation: Breslow, R.

Chem. Soc. ; Matsuda, Y /. Orgonomet. Chem. 1990, 382,19. 47. ; Kitamura, M. Pure Appl. Chem. ; Noyori, R. J. Am. Chem. Soc. 1989, HI, 4028. 48. ; Nakai, T. J. Chem. Soc, Chem. Commun. ; Terada, M. Tetrahedron Symposia in Print 1992,48, 5677. 49. Heathcock, C. H. Chem & Eng. News 1991, 3. 50. ; Caughlan, C. N. Inorg. Chem. 1966, 5, 1782. ; Takusagawa, F. Organometallics 1994, 13, 2218. 51. Figure 2 represents the 3-D representation rendered with the Macintosh program Chem-3D+. Bond lengths and angles of the Ti202 four membered ring and titanium binaphthoxide framework were initially based on the X-ray crystal analysis data for a similar type of diphenoxytitanium dichloride and diisopropoxytitanium binaphthoxide, which was generously presented by Professor K.

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